A compound with the formula C9H8O3 shows a strong hand at 1661 cm–1 in the infrared spectrum. The proton NMR spectrum is shown, but there is a small impurity peak at 3.35 ppm that should be ignored. Expansions are shown for the downfield protons. In addition, the normal carbon-13, DEPT-135, and DEPT-90 spectral results are tabulated.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%
A compound with the formula C9H8O3 shows a strong hand at 1661 cm–1 in the infrared spectrum. The proton NMR spectrum is shown, but there is a small impurity peak at 3.35 ppm that should be ignored. Expansions are shown for the downfield protons. In addition, the normal carbon-13, DEPT-135, and DEPT-90 spectral results are tabulated.
1. Deduce the structure of this compound from these spectra.
10
3
1
Transcribed Image Text:1. Deduce the structure of this compound from these spectra. 10 3 1
140
130
7.0
(ppm)
C3H3O3
Normal Carbon
DEPT-135
DEPT-90
26 ppm
Positive
No peak
102
Negative
No peak
107
Positive
Positive
108
Positive
Positive
125
Positive
Positive
No peak
No peak
No peak
No peak
No peak
No peak
No peak
No peak
132
148
151
195
Transcribed Image Text:140 130 7.0 (ppm) C3H3O3 Normal Carbon DEPT-135 DEPT-90 26 ppm Positive No peak 102 Negative No peak 107 Positive Positive 108 Positive Positive 125 Positive Positive No peak No peak No peak No peak No peak No peak No peak No peak 132 148 151 195
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 5 steps with 1 images

Blurred answer
Knowledge Booster
NMR Spectroscopy of Organic Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY