A 1.000 ml aliquot of a solution containing Cu* and Ni* is treated with 25.00 mL of a 0.03468 M EDTA solution. The solution is then back titrated with 0.02308 M Zn* solution at a pH of 5. A volume of 20.28 ml. of the Zn solution was needed to reach the xylenol orange end point. A 2.000 ml aliquot of the Cu* and Ni* solution is fed through an ion- exchange column that retains Ni. The Cu+ that passed through the column is treated with 25.00 mL of 0.03468 M EDTA. This solution required 23.18 mL of 0.02308 M Zn* for back titration. The Ni?+ extracted from the column was treated witn 25.00 mL of 0.03468 M EDTA. How many milliliters of 0.02308 M Zn* is required for the back titration of the Ni+ solution?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.33QAP
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A 1.00 mL aliquot of a solution containing Cu and Ni is treated with 25.00 ml. of a 0.03468 M EDTA solution. The
solution is then back titrated with 0.02308 M Zn+ solution at a pH of 5. A volume of 20.28 ml. of the Zn solution was
needed to reach the xylenol orange end point. A 2.000 mL aliquot of the Cu* and Ni* solution is fed through an ion-
exchange column that retains Ni?*. The Cu?+ that passed through the column is treated with 25.00 mL of 0.03468 M
EDTA. This solution required 23.18 mL of 0.02308 M Zn* for back titration. The Ni extracted from the column was
treated witn 25.00 mL of 0.03468 M EDTA.
How many milliliters of 0.02308 M Zn+ is required for the back titration of the Ni solution?
volume:
ml.
Transcribed Image Text:A 1.00 mL aliquot of a solution containing Cu and Ni is treated with 25.00 ml. of a 0.03468 M EDTA solution. The solution is then back titrated with 0.02308 M Zn+ solution at a pH of 5. A volume of 20.28 ml. of the Zn solution was needed to reach the xylenol orange end point. A 2.000 mL aliquot of the Cu* and Ni* solution is fed through an ion- exchange column that retains Ni?*. The Cu?+ that passed through the column is treated with 25.00 mL of 0.03468 M EDTA. This solution required 23.18 mL of 0.02308 M Zn* for back titration. The Ni extracted from the column was treated witn 25.00 mL of 0.03468 M EDTA. How many milliliters of 0.02308 M Zn+ is required for the back titration of the Ni solution? volume: ml.
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