8) The equilibrium constant K for a certain chemical reaction has been determined experimentally and is described by the following equation between 400 K and 600 K: In (K) = A + BT- + CT-² , where A, B, and C are constant with the values A = -1.76, B = -1368 K, and C = 1.1 × 10° K². Calculate the standard reaction enthalpy A,H® and the standard reaction entropy A,S® at T = 500 K. Hint: It will be useful to start from the expression for the derivative of In (K) with respect to 1/T: dIn (K) d(1/T) A,H° (van't Hoft equation) R to fnd Δ, Η9.

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Chapter17: Spontaneity, Entropy, And Free Energy
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Problem 112CWP: The equilibrium constant for a certain reaction increases by a factor of 6.67 when the temperature...
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8) The equilibrium constant K for a certain chemical reaction has been determined
experimentally and is described by the following equation between 400 K and 600 K:
In (K) = A + BT¬ + CT-² ,
where A, B, and C are constant with the values A = -1.76, B = -1368 K, and
C = 1.1 x 105 K?. Calculate the standard reaction enthalpy A,H° and the
standard reaction entropy A,Sº at T = 500 K.
Hint: It will be useful to start from the expression for the derivative of In (K) with
respect to 1/T:
d In (K)
d(1/T)
4,H°
(van't Hoft equation)
R
to find A, Hº.
Transcribed Image Text:8) The equilibrium constant K for a certain chemical reaction has been determined experimentally and is described by the following equation between 400 K and 600 K: In (K) = A + BT¬ + CT-² , where A, B, and C are constant with the values A = -1.76, B = -1368 K, and C = 1.1 x 105 K?. Calculate the standard reaction enthalpy A,H° and the standard reaction entropy A,Sº at T = 500 K. Hint: It will be useful to start from the expression for the derivative of In (K) with respect to 1/T: d In (K) d(1/T) 4,H° (van't Hoft equation) R to find A, Hº.
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