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7. Figure 5.1 shows the absorption and emission spectrum of a molecule in solution. (a) identify the radiative processes leading to these three peaks. (b) Estimate the energy difference, in eV's, between the ground state S. and the first excited singlet state, S₁. (c) Estimate the energy differ- ence between the S, and T, states, in eV's. What assumption is being made in this calculation? 450nm 550nm 675nm 400 600 700 500 Anm

7. Figure 5.1 shows the absorption and emission spectrum of a molecule in solution. (a) identify the radiative processes leading to these three peaks. (b) Estimate the energy difference, in eV's, between the ground state S. and the first excited singlet state, S₁. (c) Estimate the energy differ- ence between the S, and T, states, in eV's. What assumption is being made in this calculation? 450nm 550nm 675nm 400 600 700 500 Anm

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter4: Introduction To Quantum Mechanics
Section: Chapter Questions
Problem 39P: Chapter 3 introduced the concept of a double bond between carbon atoms, represented by C=C , with a...
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Figure 5.1 shows the absorption and emission spectrum of a molecule in solution. (a) ideritity the radiative processes leading to these three peaks. (b) Estimate the energy difference, in eV's, between the ground state S and the first excited singlet state, S, . (c) Estimate the energy difference between the S, and I, states, in eV's. What assumption is being made in this calculation? ? 7. Figure 5.1 shows the absorption and emission spectrum of a molecule in solution. (a) identify the radiative processes leading to these three peaks. (b) Estimate the energy difference, in eV's, between the ground state S. and the first excited singlet state, S₁. (c) Estimate the energy differ- ence between the S, and T, states, in eV's. What assumption is being made in this calculation? 450nm 550nm 675nm 400 600 700 500 2. nm
Transcribed Image Text:Figure 5.1 shows the absorption and emission spectrum of a molecule in solution. (a) ideritity the radiative processes leading to these three peaks. (b) Estimate the energy difference, in eV's, between the ground state S and the first excited singlet state, S, . (c) Estimate the energy difference between the S, and I, states, in eV's. What assumption is being made in this calculation? ? 7. Figure 5.1 shows the absorption and emission spectrum of a molecule in solution. (a) identify the radiative processes leading to these three peaks. (b) Estimate the energy difference, in eV's, between the ground state S. and the first excited singlet state, S₁. (c) Estimate the energy differ- ence between the S, and T, states, in eV's. What assumption is being made in this calculation? 450nm 550nm 675nm 400 600 700 500 2. nm
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