Answered: 5. Use the following experimental…

5. Use the following experimental values: a. Determine the following: i. Rate Law ii. Overall reaction order iii. Calculate the value of the rate constant.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.26E: a Write a rate law and an integrated rate law for a chemical reaction that follows third-order...

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Question

See table in picture

Consider the table of initial rates for the reaction: 2C1O₂ + 20H¹ → C10,¹ + ClO₂ + H₂O.
Experiment
[CIO₂]o, mol/L
[OH¹] ., mol/L
Initial Rate, mol/(Ls)
1
0.050
0.100
5.75 x 10 2²
2
0.100
0.100
2.30 x 10r¹
3
0.100
0.050
1.15 x 10¹¹

5. Use the following experimental values:
a. Determine the following:
i. Rate Law
ii. Overall reaction order
iii. Calculate the value of the rate constant.
b. What experimental data would you need to
plot to get a straight line graph for a second
order kinetic study? Make a graph showing
the proper relationship.
DE

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