3. Given the following names of organic compounds, draw a suitable structure using wedges and hashed lines only where necessary: (Remember, 6 atoms lie in the plane of each double bond!) (a) 3,3-dimethyl-1-pentene (b) R-1,4-dimethylcyclohexene (c) 2-trans-4-cis-2,4-heptadiene (d) cis-2,3-diethyloxirane

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* Pill in the following blanks A cycloalkadiene with 8 cartons will have the molecular formula
CH An alkene cowtains wo dirferent bonds between Csp carbons called a
bond
and a
bond. The double bonds in vegetable oils and natural rubber all have the
configuration. Oily liquid fatty acid esters in peanut butter can be turned into solids by catalytic
over a metallic Pd (or Ni) catalyst. The anti-addition of bromine to cyclohexene
gives
-1,2-dibromocyclohexane. A 2° alkyl bromide is produced when
is
added to a trans-disubstituted alkene.
2. Answer the following questions using only the terms Less or More.
heat is evolved
during catalytic hydrogenation of disubstituted alkene than with a trisubstituted alkene. In addition
reactions of H-X to an alkene, the proton is attached to the
-substituted carbon. The
addition of borane (BH3) to a 1-alkene gives an alkylborane with the boron bonded to the
substituted carbon. A 3° carbocation is
stable than a 2° carbocation.
3. Given the following names of organic compounds, draw a suitable structure using wedges and
hashed lines only where necessary: (Remember, 6 atoms lie in the plane of each double bond!)
(a) 3,3-dimethyl-1-pentene
emes if approprate
(b) R-1,4-dimethylcyclohexene
(c) 2-trans-4-cis-2,4-heptadiene
the following
(d) cis-2,3-diethyloxirane
4. Name the following compounds:
(a)
(6)
(c)
+H-
(d)
Transcribed Image Text:* Pill in the following blanks A cycloalkadiene with 8 cartons will have the molecular formula CH An alkene cowtains wo dirferent bonds between Csp carbons called a bond and a bond. The double bonds in vegetable oils and natural rubber all have the configuration. Oily liquid fatty acid esters in peanut butter can be turned into solids by catalytic over a metallic Pd (or Ni) catalyst. The anti-addition of bromine to cyclohexene gives -1,2-dibromocyclohexane. A 2° alkyl bromide is produced when is added to a trans-disubstituted alkene. 2. Answer the following questions using only the terms Less or More. heat is evolved during catalytic hydrogenation of disubstituted alkene than with a trisubstituted alkene. In addition reactions of H-X to an alkene, the proton is attached to the -substituted carbon. The addition of borane (BH3) to a 1-alkene gives an alkylborane with the boron bonded to the substituted carbon. A 3° carbocation is stable than a 2° carbocation. 3. Given the following names of organic compounds, draw a suitable structure using wedges and hashed lines only where necessary: (Remember, 6 atoms lie in the plane of each double bond!) (a) 3,3-dimethyl-1-pentene emes if approprate (b) R-1,4-dimethylcyclohexene (c) 2-trans-4-cis-2,4-heptadiene the following (d) cis-2,3-diethyloxirane 4. Name the following compounds: (a) (6) (c) +H- (d)
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