5 14.Draw 3-5 constitutional isomers of each of the following, then for each of the following: (1) name each isomer,(2) circle the isomer with the highest boiling point, and (3) identify all tertiary carbons (also by circling) in the moleculesyou have drawn.a. CHjoBrzb. CH12c. CaHoBrzd. CHule. CaHClf. CHaF

The isomers which have same molecular formula but they have different connectivity connectivity of…

Answered: 14. Draw 3-5 constitutional isomers of…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter2: Chemical Compounds

Section2.9: Organic Molecular Compounds

Problem 2.12E

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Arrange the following in DECREASING order of boiling point. heptane 2,4-dimethylpentane 3-methylhexane II II O a. I| > III >| O b. III > || >| O c. T> III >|| Ос. |> I|| O d. III> I > ||
15. a. Draw two constitutional isomers with the formula CaHsBrCl ( Isomer 1 Isomer 2 b. Describe ALL the intermolecular forces isomer 1 can participate in 16. For the molecule below, OH (a) Circle all functional groups present. (b) Label two of the functional groups next to where you circled them 3
3. Though they have similar structures, the boiling points of the molecules depicted below differ significantly. Why? -HO- -HO- Acetic Acid Ethanol BP = 117.9 C BP = 78.4 C %3D
b. Consider the equilibrium shown below. When the solvent is ethanol (CH3CH₂OH), conformer B is preferred. However, when the solvent is carbon tetrachloride (CCl4), conformer A is preferred. Use drawings to illustrate the non-covalent interactions responsible for the different conformational preference in these two different solvents. Minimal text may be used to further support your explanation. OH A OH НО B OH
9. Give the compound name, functional group name, and organic family name in each Ose. Classify alcohols as primary (1°), secondary (2 ), or tertiary (3"). Organic family Functional Formula Compound name group name CH3-CHz-CH-CH2-OH 1. CH3 CH,-CH,-0-CH,-CH,-CH, || CH,-CH, C-H CH CH,-C-CH-CH,-CH, CH-CH-CH- CH- COOH
15. For the molecules:2,2-dimethylhexane, and octane. Which of the 2,3,4-trimethylpentane following structures will have the highest bp, lowest mp, and the least soluble in water?
1. Is this molecule is saturated? Explain your reasoning. нннн Н-с—С—С-с-н H HHH
Rewrite each of these structures as a condensed structure. H F\H H H-C-Ċ-Ċ –Ċ-H H FHH condensed structure: CH3CF2CH2CH3 H H нНН H. H-С—С—С—Н H O H. 1 H. condensed structure: CH-3-CH-CH3
12. Write bond-line structural formulas for (a.) two primary alcohols, (b.) a secondary alcohol, and (c.) a tertiary alcohol-all having the molecular formula CaH100.
Convert each compound to a condensed structure. H. H-C-H H H H 1. a. H-C-C-C-C-C-H H HH H H-C-H H HHC: HH I I I I b. H-С-с--с-с-с-н :Br: H HHH H H. HHH c. H-C-C- C-0-C-C-C-H H. H-C-H H H H HHH O: d. H-C-C-C-C-H HHH CIH
11. Circle and label all functional groups of the following molecules. a). Nepetalacon, the active ingredient of catnip: HC CH b). Methyl stressonate, isolated from the sweat of students taking organic finals: HC CH, N(CH,)2 QCH3 ÓCH, c). Xenical, a weight loss drug that work by irreversibly blocking stomach and intestinal enzymes involved in fat metabolism
3. Name all the functional group/s in the following organic compound. This is the chemical compound 'capsaicin' - the source of the heat in hot chili peppers. HHOH H HHH H -C-C-C-C-C%3DC-C-CH3 T T T T H HHH -C-N-C-C- H CH3 a. b. H. H. C- H3C-O C-C- C-C C. d.

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