1. In which direction does the equilibrium lie for each of the following reactions? Use thedata in the Table to determine in which direction the equilibrium lie for each of thefollowing reactions?a. CH3CO2H + CH3CH2Ob. CH3CONH2 + FCH3CO2 + CH3CH2OHCH3CONH + HEC. H20 + NH2OH + NH3 The pK, values for types of compounds frequently encountered inorganic chemistry.Table 5.1pkaCompound typesMineral acids (H2SO4, HI, HBr, HCI); sulfonic acids (RSO3H)H30*, H3PO4Carboxylic acids (RCOO H), HF, aromatic thiols (ArSH), HN3Weak inorganic acids (H2S, HCN, NHa*), amine salts (RNH3*), phenols (ArOH),thiols (RSH), aromatic amides (ArCONHH20, alcohols (ROH), amides (RCONH2)-105101520Ketones (RCH2COR')25Esters (RCH,COOR'), alkynes (RC=CH), nitriles (RCH2CN)Anilines (ARNH2)Ammonia (NH3), amines (RNH2), benzylic C-H (ArCH2X)304045Arenes (ArH) and alkenes (RCH=CH2)50Alkanes (RH)

With the help of pKa table in hand, we have to predict the equilibrium direction of following…

1. In which direction does the equilibrium lie for each of the following reactions? Use the data in the Table to determine in which direction the equilibrium lie for each of the following reactions? a. CH3CO2H + CH3CH2O¯ b. CH3CONH2 +F CH3CO2 + CH3CH2OH CH3CONH + HF C. H2O + NH2 OH + NH3

1. In which direction does the equilibrium lie for each of the following reactions? Use the data in the Table to determine in which direction the equilibrium lie for each of the following reactions? a. CH3CO2H + CH3CH2O¯ b. CH3CONH2 +F CH3CO2 + CH3CH2OH CH3CONH + HF C. H2O + NH2 OH + NH3

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

1. In which direction does the equilibrium lie for each of the following reactions? Use the
data in the Table to determine in which direction the equilibrium lie for each of the
following reactions?
a. CH3CO2H + CH3CH2O
b. CH3CONH2 + F
CH3CO2 + CH3CH2OH
CH3CONH + HE
C. H20 + NH2
OH + NH3

The pK, values for types of compounds frequently encountered in
organic chemistry.
Table 5.1
pka
Compound types
Mineral acids (H2SO4, HI, HBr, HCI); sulfonic acids (RSO3H)
H30*, H3PO4
Carboxylic acids (RCOO H), HF, aromatic thiols (ArSH), HN3
Weak inorganic acids (H2S, HCN, NHa*), amine salts (RNH3*), phenols (ArOH),
thiols (RSH), aromatic amides (ArCONH
H20, alcohols (ROH), amides (RCONH2)
-10
5
10
15
20
Ketones (RCH2COR')
25
Esters (RCH,COOR'), alkynes (RC=CH), nitriles (RCH2CN)
Anilines (ARNH2)
Ammonia (NH3), amines (RNH2), benzylic C-H (ArCH2X)
30
40
45
Arenes (ArH) and alkenes (RCH=CH2)
50
Alkanes (RH)

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