1. A similar experiment as this lab is done as following: 0.456 g of solid AgCl is added a 25 mL solution of a 1.05 M ligand L to form complex AgL+. AgCl (s) + L (aq) → AgL+ (aq) + Cl- (aq) When the reaction is complete, 0.315 g of solid AgCl remains. Assume the total volume of the resultant solution is the same as the volume of the ligand solution. Ksp of AgCl in water is 1.83 x 10-10. Complete the following tasks: a) Calculate the equilibrium concentrations of [AgL+]eq and [Cl-]eq. b) Calculate the equilibrium concentration of [L]eq. c) Calculate the equilibrium constant K of this reaction: AgCl (s) + L (aq) → AgL+ (aq) + Cl- (aq) K =? d) Calculate the formation constant Kf of AgL+. Ag+(aq) + L(aq) → AgL+(aq) Kf= ?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter15: Additional Aqueous Equilibria
Section: Chapter Questions
Problem 123QRT: You are given four different aqueous solutions and told that they each contain NaOH, Na2CO3, NaHCO3,...
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1. A similar experiment as this lab is done as following: 0.456 g of solid AgCl is added a 25 mL
solution of a 1.05 M ligand L to form complex AgL+.
AgCl (s) + L (aq) → AgL+ (aq) + Cl- (aq)
When the reaction is complete, 0.315 g of solid AgCl remains.
Assume the total volume of the resultant solution is the same as the volume of the ligand
solution. Ksp of AgCl in water is 1.83 x 10-10.
Complete the following tasks:
a) Calculate the equilibrium concentrations of [AgL+]eq and [Cl-]eq.
b) Calculate the equilibrium concentration of [L]eq.
c) Calculate the equilibrium constant K of this reaction:
AgCl (s) + L (aq) → AgL+ (aq) + Cl- (aq) K =?
d) Calculate the formation constant Kf of AgL+.
Ag+(aq) + L(aq) → AgL+(aq) Kf= ?
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