1. 2. BH3 a = Proton transfer b = Lewis acid/base 1. N(CH3)3 2. NaOEt EtOH CH3 H₂B-N-CH3 CH3 + NaCl + e Electrophilic addition f = E1 Elimination g = E2 Elimination HOEt Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a -j for your answers. h SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution j = Electrophilic aromatic substitution 12a
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- 1. 2. OH a Proton transfer b = Lewis acid/base c = Electrophilic addition 1. CH3OH 2. H₂SO4 130⁰ OCH3 d e HCI H₂O E1 Elimination E2 Elimination The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a - g for your answers. f = SN1 Nucleophilic substitution g = SN2 Nucleophilic substitutionChemistry 1. 2. ů. + 1. CH₂OH a= Proton transfer b= Lewis acid/base c = Radical chain substitution d Radical chain addition = 2. Aqueous acetone OCH₂ + Y HO e Electrophilic addition f E1 Elimination g = E2 Elimination HCI Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a- j for your answers. h= S1 Nucleophilic substitution i= SN2 Nucleophilic substitution j= Electrophilic aromatic substitution1. 2. -CH3 1. tom 2. OH + aqueous H₂SO4 a Proton transfer = b = Lewis acid/base c = Radical chain substitution HBr OH CH3 ti Br d = Radical chain addition e = Electrophilic addition f = E1 Elimination Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution
- 1. 2. Ph 1. Ph OH a Proton transfer b = Lewis acid/base c = Electrophilic addition 2. + Na CN NMe₂ DMF H₂SO4 Ph Ph H3C H CH3 H CN OH NM²₂ Tamoxifen anti (brest) cancer drug Ph d E1 Elimination = e = E2 Elimination Ph NMe₂ The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a- g for your answers. f = SN1 Nucleophilic substitution gSN2 Nucleophilic substitution1. 2. NaOH 1. OH 2. H3C-1 a = Proton transfer b = Lewis acid/base C = Electrophilic addition + NaHCO3 H3C-OH int d = E1 Elimination e = E2 Elimination Nal H₂O CO₂ Nal The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a - g for your answers. f = SN1 Nucleophilic substitution g = SN2 Nucleophilic substitution2. a = Proton transfer b = Lewis acid/base C = Electrophilic addition Na CN 1. 2. conc. HBr DMF CH3 H OH H3C H CN OH d = E1 Elimination e = E2 Elimination Bit Bri The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a- g for f = SN1 Nucleophilic substitution g = SN2 Nucleophilic substitution your answers.
- 1. 2. NaOEt a Proton transfer = b = Lewis acid/base c = Electrophilic addition 1. Mg2+ Br 2. EtOH H₂SO4/H₂O + + NaCl H₂O + HOEt Mg2+ Br d E1 Elimination e = E2 Elimination. HSO₁ The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a-g for your answers. f = SN1 Nucleophilic substitution g SN2 Nucleophilic substitution =1. 2. H₂C 1. MeO 2. -CH3 H₂O a = Proton transfer b = Lewis acid/base c = Radical chain substitution H3PO4 80° MeO CH3 H₂COM₂ CH3 d = Radical chain addition e = Electrophilic addition f = E1 Elimination H₂O Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution1. 2. CH3 a 1. www 2. CH3 + Br a = Proton transfer b = Lewis acid/base c = Radical chain substitution HCI مار Na benzene, reflux CH₂ d CI d Radical chain addition e = Electrophilic addition f = E1 Elimination 4 HO-CH + NaBr Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution
- 1. 2. HO H + 2. + KOt-Bu SOCI₂ a = Proton transfer b = Lewis acid/base C = Electrophilic addition d = E1 Elimination e = E2 Elimination H + KCI + Hot-Bu SO₂ + HCI f = SN1 Nucleophilic substitution g = SN2 Nucleophilic substitution The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a - g for your answers.b) Rank the following alcohols from the most to the least acidic. (liic. НО. CI I но. I || Н ОН I HO CHO H3C-C-CH3 H-C-н Н CH3 " ОН ОН IV c) Indicate the oxidation state for each of the carbon atoms highlighted in red. v. НО F F H-O-OH H₂C-C-H н-с-он V ОН H3C-"-н H3C-C-CH3 ОН IV V1. 2. OH a = Proton transfer b Lewis acid/base c = Radical chain substitution 1. NaOH 2. H₂N S NH₂ Na d = Radical chain addition e = Electrophilic addition f = E1 Elimination H₂O +NH₂ NH₂ CI Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g= E2 Elimination SN1 Nucleophilic substitution h = i = SN2 Nucleophilic substitution