Buffers, Henry’s Law Discussion Workshee

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School

Sierra College *

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1A

Subject

Chemistry

Date

Oct 30, 2023

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pdf

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6

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More Equilibri a BUFFERS, HENRY’s LAW jon to Gradescope: fe Jor submiss ope: no later than 1]:59 pue s ,discusslon section meels (e.g., Wed. discu 42 pm o the second you Sjif-".l I-).y:] 1:59 pm on Friday, el‘é‘gendar day Wr ,{' Curves Discuss the titration curves 61 the Tast : itration o e last page of this assi beiloving gnment and then do fh ation Of 2 frett omL HCI with NaOH is shown for your reference in the graphs below (on this ¢ and the following). The dgtted line indicatds a-pH of 7. In the reference titration curv the HCl has a concentration of 0.10M and the NaOH added along the x-axis has a B wncentration of 0.10M. In each of the graphs, sketch another titration curve for the conditions cified at the top of each graph. Your sketches can be rough, but be sure to o €Xp explain your choice for the vol the reference mark the equivalence point with a X explain your choice for the pH at the end on your n lain your choice for the initial pH on your new curve relative to the reference ' ume at the equivalence point on your new curve relative to ew curve relative to the reference B S g e 20l of 0.10M weak 20 mL of 0.20M strong 20 mL of 0.10M strong acid is titrated with acid is titrated with ba:g;: :Itgted with 0. 0.10M NaOH ERFZ=asgili==v=sE 0.10M NaOH pH .—-_._'- ’.—.— -E\/EI:E;H_:E ’:;Tohlme of Tfi‘a}}-}"} % : -0 l.“ne [\ ltl(.ult & m T o e £ . o W@%fi%v wid, | Vi Oluye of Titrant dnt Bice | Bug Ihe erg con : & mge - " Other Equilibria M PW is © Regents of the University of California. 2022. ) Scanned with CamScanner 's,\w'm ‘;c/l'hcpfi’) b figged 6L Sohe
Page 34 / 20 mL Olt' O}Zegh;i filrong .IOMHCIIS base is fifra s 0.10M HCI titrated with 0.05M NaOH ¥ n . pH _—: o’ !_/ =5 = _ Volume of Titrant Volume of Titrant sOME volupr % vl cofcertroion of e a0 8 dpe saltrots.. . Weaieraald, bt~ wh a_ lower D & i ront, go ptiag Higpect wih ol iy Mojenee 2, Ut o e o, G2 i ifornia, © Regents of the University of Califo! 20 mL o g1 . - 10M base is titry ed wi:lv]eak 0.10M HCl i ll 1 pH T E= Volume of Timt\ L gt is hecause a 2022 Scanned with CamScanner
2 Thinking about buffer solutions W A buffer solution contains both a weak acid and its njugate base. Buffers resist large changes of pH con upon addition of strong acids or bases. HX(aq) + H0() = H30%(aq) + X (aq) Ka = [H:0"1IIX] _ [H30+][00fliugate base] 2= [HX] [conjugate acid] _oK. + | [conjugate base] phi=Phaufied [conjugate acid] puffer Range [ ] Useful info: pH = pK, + log log(1) =0 pH% [HA] log(10/t) =1 log(1/10) = -1 E.P 119 Al pK,+ 1 ol P T Base form pKa- 1 [77Acid form dominates dominates —> v EP a weak acid HA is titrated with NaOH. When 0.51 moles of (a) A solution containing 1 mole of NaOH have been added to solution, which of these has the greatest concentration? (a) HA (c) OH~ (b) Which, when added to an NH3 sotution, forms a basic buffer (i.e., with pH > " (a) NaOH @aCl (c) HC1 Page 35 © Regents of the University of California, 2C Buffers, Other Equilibria Scanned with CamScanner
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