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- (b) Predict the suitable solvent (H2O or CH3COCH3) to increase the reaction of bromopropane (CH3CH2CH2B1) with sodium hydroxide (NaOH). Two reactions are shown below: NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + NaBr H,O (i) NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH NaBr H,C CH (ii)A medicinal chemist at Orgalex Labs, a little known division of a big international pharmaceutical firm, has predicted the major product of the following reacti an early step in the synthesis of Compound R40 (rumored to be a cure for rhinitis, spontaneous combustion, and bad luck): or=0x0 HBr OH As Vice-President of Research, it's your job to decide whether the chemist has made a reasonable prediction. • If your answer is yes, these could be the major products of the reaction, draw the complete mechanism for the reaction below. • If your answer is no, check the box under the drawing area. Ö U OH Br H-Br Add/Remove step Click and drag to start drawing a structure.(d) When butane, CH3CH2CH2CH3 and bromine gas, Br2 is exposed to sunlight, monobrominated product are produced. The reaction equation is given below: uv CH;CH,CH,CH3 + Br2 A + B (i) State the type of reaction. (ii) What is the function of the sunlight in the reaction? (iii) Draw the structure of monosubstituted products, A and B. Label the major product. (iv) Draw the propagation steps in the mechanism for the formation of the major product.
- 5) The following question concerns redox methodology: Present answers in the form of structures, mechanisms, reagents or explanations for the arrows associated with the following reductions: give a structure Ph. a) i) LIAIH, / ether /-10°C C3H100 CO,Me ii) H20 A Present a mechanism give reagents Lindlar Comment on the chemo- and b) stereoselectivity. give reagents and conditions CO,Me CO,Me Birch Present a mechanism and hence c) explain the regioselectivity 100% 0%(b) Reactivity with the S1 by the treatment with NaOH Br Br I t 2 (c) Solubility in hexane: Br H3C-BrIdentify the reagent used in the following transformation: OH P Q HO HO P = LIAIH, Q = KMNO, Q = MnO, / CH,Cl, Q = Ag,CO, on celite, PhH (A) (B) P= NABH, /MeOH %3D (C) P=CeCl,.7H,O (D) P= NABH, /CeCl,.7H,0 , / CeCly.7H,O Q = MnO, / CH,Cl,
- (b) From the following molecules, A-D, a rotaxane can be formed. B NH i. ii. A HN H 'N C H D Cd(CIO4)2 NH₂ Draw the structure of the possible rotaxane that can be formed by molecules A-D. Give the order you would add the above molecules in order to synthesise a rotaxane. Justify your chosen order.(a) Tsomane and Nyiko were given a task of synthesising methylenecyclohexane 2. After a brief discussion with each other, Tsomane proposed Method A to synthesise 2 from cyclohexanone 1 while Nyiko proposed Method B that started from hydroxymethylcyclohexane 3. Each student believed that their proposed method is better than the other. (Scheme below) (1) Ph Ph 8*8 Ph THF A 1 Santande B H₂SO4 100 °C 3 OH Using curly arrows, provide full mechanistic details accounting how methylenecyclohexane 2 was synthesised according to both Methods A and B.3. (a) Complete the following reactions and write the name of products (i) 1. HNO3, H2SO4 AICI3 2. Zn(Hg), HCI (ii) 1. HBr 2. NaOCH3 3 (iii) ??? H2N-NHCON2 Aq. KOH C6H5CH2OH → BENZALDEHYDE A В (b)What happens when (write reactions involved) (iv) Phenol reacts with sodium metal and resulting product reacts with 2-chloropropane (v) Ethanal reacts with HBr and the resulting product is dehydrated (vi) Ethoxyethane is hydrolyzed to produce a compound A which dehydration produces B. B on ozonolysis produces C. Write the reaction and identify A, B, and C.
- 3. Provide the products, intermediates, and/or reagents for the following reactions: (a) CH3 (i) H2N CH3 pyridine Ph (b) он PBr3 PPh, кови (ii) (iii) (iv) then (c) Ph Br. (v) CH3 (d) HNO, (excess) (vi) CH3 H2SO4 (e) 2 Li(s) Ph-CEN (vii) (viii) then HCI, H20 HO (x) (1) DIBAL-H HO t-Bu, (ix) then NaOH, H20 p-TSOH (g) NH2 CH3 (xi) Но pyridine Но10. The following reaction has variation of free energy value of AG = -2.1 kJ/mol CH;Br + H2S 2 CH;SH + HBr (a) Calculate Keq at room temperature (25°C) for this reaction as written. (b) Starting with a 1 M solution of CH3B and H2S, calculate the final concentrations of all four species at equilibrium.Write the formula of reagents used in the following reactions:(i) Bromination of phenol to 2,4,6-tribromophenol(ii) Hydroboration of propene and then oxidation to propanol.(b) Arrange the following compound groups in the increasing order of their property indicated:(i) p-nitrophenol, ethanol, phenol (acidic character)(ii) Propanol, Propane, Propanal (boiling point)