Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Chapter15: Carboxylic Acids And Esters
Section: Chapter Questions
Problem 15.54E
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Question
As we will learn in Section 13.12, many antioxidants–compounds that prevent unwanted radical oxidation reactions from occurring–are phenols, compounds that contain an OH group bonded directly to a benzene ring.
a. Explain why homolysis of the O–H bond in phenol requires considerably less energy than homolysis of the O–H bond in ethanol (362 kJ/mol vs. 438 kJ/mol).
b.Why is the C–O bond in phenol shorter than the C–O bond in ethanol?
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