Evaluate the specific rate constant for the reaction at the temperature for which the data were obtained. The rate-law expression is rate = k[A][B]2. A + B  C Experiement Initial [A] Initial [B] Initial Rage of Formation of C 1 0.10 M 0.10 M 4.0 ´ 10-4 M/min 2 0.20 M 0.20 M 3.2 ´ 10-3 M/min 3 0.10 M 0.20 M 1.6 ´ 10-3 M/min       6.2 × 10-1 M-2•min-1     4.0 × 10-1 M-2•min-1     1.2 × 10-2 M-2•min-1     7.0 × 10-3 M-2•min-1

Chemistry by OpenStax (2015-05-04)
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ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter12: Kinetics
Section: Chapter Questions
Problem 4E: A study of the rate of dimerization of C4H6 gave the data shown in the table: 2C4H6C8H12 (a)...
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  1. Evaluate the specific rate constant for the reaction at the temperature for which the data were obtained. The rate-law expression is rate = k[A][B]2.

    A + B  C

    Experiement

    Initial [A]

    Initial [B]

    Initial Rage of Formation of C

    1

    0.10 M

    0.10 M

    4.0 ´ 10-4 M/min

    2

    0.20 M

    0.20 M

    3.2 ´ 10-3 M/min

    3

    0.10 M

    0.20 M

    1.6 ´ 10-3 M/min

     

       

    6.2 × 10-1 M-2•min-1

       

    4.0 × 10-1 M-2•min-1

       

    1.2 × 10-2 M-2•min-1

       

    7.0 × 10-3 M-2•min-1

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