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- Draw the product of the reaction shown below at physiological pH (pH = 7.4). Ignore inorganic byproducts. XY IZ N O SH ZI H₂N, N CF3CO2H CO ofDraw the product of the reaction shown below at physiological pH (pH = 7.4). Ignore inorganic byproducts. I Toin N N H CF3CO2H Drawing Q← Problem 18 of 24 Draw the product of the reaction shown below. Ignore inorganic byproducts. pTsCl N(CH2CH3)3 • OH Submit Q
- Draw the major product of this reaction. Ignore inorganic byproducts. Assume that the water side product is continuously removed to drive the reaction toward products. € O (CH₂OH)2, TSOH Adjetiocntcon com I I AGROCHES 1 Commirahat DERMINECROMANIAN U U I FAMES MORONIFUOT 10 N ----Provide the products and detailed arrow pushing mechanisms for the following reactions: OSIME3 EtN CO.Me 1. base, dilute solution (10mM) 2. NaOH/MEOH-H,0 Acid, heat CO.MePredict the products, if any, of the following reactions. 20-35 (a) ascorbic ac (1) LiAlH4 -COOH (2) H3O+ (b) (1) NaCN CH₂Br (2) H3O+, heat (c) (1) SOCl2 (d) KMnO4, H₂O oct-4-yne (warm, concd.) (2) AlCl3 COOH (e) CH₂OH Na2Cr2O7, H2SO4 (f) Ph (1) BH3.THF CH3CH2-CH-COOH (2) H₁₂O+
- As far back as the 16th century, South American Incas chewed the leaves of the coca bush, Erythroxylon coca, to combat fatigue. Chemical studies of Erythroxylon coca by Friedrich Wöhler in 1862 resulted in the discovery of cocaine, C17H21NO4, as the active component. Basic hydrolysis of cocaine leads to methanol, benzoic acid, and another compound called ecgonine, C9H15NO3. Oxidation of ecgonine with CrO3 yields a keto acid that readily loses CO2 on heating, giving tropinone. (a) What is a likely structure for the keto acid? (b) What is a likely structure for ecgonine, neglecting stereochemistry? (c) What is a likely structure for cocaine, neglecting stereochemistry?6. Complete reaction scheme below indicating reagents, catalysts and conditions, and side product trigil bezinslog si6101fon 290b 1l (b Senines levirba 6 gaubong nasamots gniwollot ads to doinW 01 sniowl (6 CH3 40 CH3 Scansgowi (d Ege nodie) ( nsgyxo (b NO₂ 19m02 2i gniwollet sits to mainW II HOThe following reaction should under go a(n) H₂C SN1 Br NaSPh DMF A/ reaction.
- Draw the structure of the expected organic product for each of the following reduction reactions. (hint: carefully consider which reducing agent is being used, and in which order!) 1. NaOH (A) isi 2. LiAlH 3. H₂O* OH (B) OH 1. H2, Pt (C) OH 1. NaBH4 2. H₂O*102. The major products A and B in the following reaction sequence are CHO Br Br (i) PPh3 (ii) NaH (A) NaH OH (B)Draw the predicted major products of the following reactions. Ph OHC., (PhP);RhCI PHCN, A H,CCH, Grubbs I, CH,OCl, Rh(CO),CI CO R-0 B(OH)2 Pd(OAc)2 K3PO4 Pd(OAc)2 K3PO4