Chemistry   Consider a molecule of ammonia NH3. (a) Choose a suitable principal axis system and plot it with the molecule. (b) What is the approximate symmetry of the molecule? Is there any approximation that must be made to consider this symmetry? (c) What is the Hamiltonian for the rigid rotor of this molecule? Include structural parameters of the molecule.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 35P
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Chemistry

 

Consider a molecule of ammonia NH3.

(a) Choose a suitable principal axis system and plot it with the molecule.

(b) What is the approximate symmetry of the molecule? Is there any approximation that must be made to consider this symmetry?

(c) What is the Hamiltonian for the rigid rotor of this molecule? Include structural parameters of the molecule.

 

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