4. Does this reaction obey first-order or second-order kinetics? 5. Are the results consistent with the kinetics of the hydrolysis of tert-butyl chloride? Yes or no

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Time (sec)
pH
[RX]
[H30+]
Ln[RX]
0.000
7.000
0.00002344
0.0000001
-10.6610666
15.000
6.400
0.00001954
0.00000039
-10.8430469
30.000
5.410
0.00001955
0.00000389
-10.8425353
45.000
5.230
0.00001756
0.00000588
-10.94988696
60.000
5.070
0.00001493
0.00000851
-11.11213794
75.000
4.920
0.00001142
0.00001202
-11.3801444
90.000
4.840
0.00000899
0.00001445
-11.6193977
105.000
| 4.780
0.00000685
0.00001659
-11.8912619
120.000
4.750
0.00000566
0.00001778
-12.08208666
135.000
4.720
0.00000439
0.00001905
-12.33618133
150.000
4.700
0.00000349
0.00001995
-12.56569882
165.000
4.670
0.00000207
0.00002137
-13.08796195
180.000
4.670
0.00000207
0.00002137
-13.08796195
195.000
4.660
0.00000157
0.00002187
-13.3644349
210.000
4.650
0.00000061
0.00002283
-14.30980687
225.000
4.650
0.00000061
0.00002283
-14.30980687
240.000
4.640
0.00000061
0.0000229
-14.30980687
255.000
4.640
0.00000061
0.0000229
-14.30980687
270.000
4.640
0.00000061
0.0000229
-14.30980687
285.000
4.630
0.00002344
Undefined
300.000
| 4.630
0.00002344
Undefined
315.000
4.630
0.00002344
Undefined
330.000
4.630
0.00002344
Undefined
Transcribed Image Text:Time (sec) pH [RX] [H30+] Ln[RX] 0.000 7.000 0.00002344 0.0000001 -10.6610666 15.000 6.400 0.00001954 0.00000039 -10.8430469 30.000 5.410 0.00001955 0.00000389 -10.8425353 45.000 5.230 0.00001756 0.00000588 -10.94988696 60.000 5.070 0.00001493 0.00000851 -11.11213794 75.000 4.920 0.00001142 0.00001202 -11.3801444 90.000 4.840 0.00000899 0.00001445 -11.6193977 105.000 | 4.780 0.00000685 0.00001659 -11.8912619 120.000 4.750 0.00000566 0.00001778 -12.08208666 135.000 4.720 0.00000439 0.00001905 -12.33618133 150.000 4.700 0.00000349 0.00001995 -12.56569882 165.000 4.670 0.00000207 0.00002137 -13.08796195 180.000 4.670 0.00000207 0.00002137 -13.08796195 195.000 4.660 0.00000157 0.00002187 -13.3644349 210.000 4.650 0.00000061 0.00002283 -14.30980687 225.000 4.650 0.00000061 0.00002283 -14.30980687 240.000 4.640 0.00000061 0.0000229 -14.30980687 255.000 4.640 0.00000061 0.0000229 -14.30980687 270.000 4.640 0.00000061 0.0000229 -14.30980687 285.000 4.630 0.00002344 Undefined 300.000 | 4.630 0.00002344 Undefined 315.000 4.630 0.00002344 Undefined 330.000 4.630 0.00002344 Undefined
PLOT OF In[RX] VS TIME
PLOT OF 1/RN] VS TIME
1500000
事。
40
42
44
100
200
imejinse)
Timelinsec)
4. Does this reaction obey first-order or
second-order kinetics?
5. Are the results consistent with the kinetics
of the hydrolysis of tert-butyl chloride? Yes or
no
Transcribed Image Text:PLOT OF In[RX] VS TIME PLOT OF 1/RN] VS TIME 1500000 事。 40 42 44 100 200 imejinse) Timelinsec) 4. Does this reaction obey first-order or second-order kinetics? 5. Are the results consistent with the kinetics of the hydrolysis of tert-butyl chloride? Yes or no
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